Search results for "Xanthene dye"

showing 4 items of 4 documents

Interaction of aminomethylated resorcinarenes with rhodamine B

2009

The interaction of aminomethylated resorcinarenes with a red xanthene dye, rhodamine B, was investigated in chloroform, methanol and chloroform–methanol solutions using UV-vis, NMR and fluorescence spectroscopy. Aminomethylated resorcinarenes 1 and 2 shift the rhodamine B equilibrium from the zwitterion to the lactone form unlike reference compounds 3 and 4, which do not contain tertiary amino groups at the upper rim, giving an example of how supramolecular hosts can influence the equilibrium of rhodamine B isomers.

chemistry.chemical_classificationChloroformSupramolecular chemistryGeneral ChemistryPhotochemistryCatalysisFluorescence spectroscopychemistry.chemical_compoundchemistryXanthene dyeZwitterionMaterials ChemistryRhodamine BMethanolLactoneNew Journal of Chemistry
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Synthesis of novel organic-based fluorophores – Implementation to the design of fluorogenic enzyme substrates based on the principle of in situ synth…

2020

Detection and fluorescence imaging of biologic systems requires the implementation of efficient, robust and easy-to-use tools. Conventional fluorogenic probes currently used in microbiology lack efficiency since they are based on the single chemical modification of a fluorophore bearing an optically tunable reactive group, which often leads to incomplete fluorescence quenching. The main goal of my Ph.D thesis was to develop novel fluorogenic enzymatic substrates based on the "covalent assembly" principle. This approach also named "in situ synthesis" is based on the use of domino reactions to form a fluorescent moiety starting from a "caged" non-fluorescent molecule. In our case, the bioanal…

Activation enzymatique[CHIM.ORGA]Chemical Sciences/Organic chemistryHétéro-XanthènesSynthèse in situHetero-Xanthene dyesQuinoxalinonesIn situ synthesis[CHIM.ORGA] Chemical Sciences/Organic chemistryEnzymatic activationFluorogenic probesSonde fluorogéniquesFluorescence
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Penicillium auxotrophic mutants can be detected by suing xanthene dyes

1987

Auxotrophic mutants ofPenicillium spp. have been directly isolated after mutagenic treatment from agar plates containing Xanthene dyes. They grow as characteristic small colored colonies. Some strains were tested and they showed a differential response depending on the Xanthene dye used.

PharmacologyXanthenebiologyAuxotrophyMutagenesis (molecular biology technique)Cell BiologyFungi imperfectibiology.organism_classificationAgar plateCellular and Molecular Neurosciencechemistry.chemical_compoundchemistryBiochemistryXanthene dyePenicilliumAuxotrophic mutantMolecular MedicineMolecular BiologyExperientia
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Synthesis, stability and spectral behavior of fluorogenic sulfone-pyronin and sulfone-rosamine dyes

2018

International audience; The first synthesis of sulfone-pyronin and sulfone-rosamine dyes bearing optically tunable primary amino groups (acting as fluorogenic centers) is presented. Sulfone analogs of xanthene-based fluorophores have recently been highlighted as a new class of near-infrared (NIR) fluorescent dyes (Liu et al. ACS Appl Mater Interfaces 2016; 8(35):22953-62), and the availability of fluorogenic derivatives is essential for the rapid construction of “turn-on” reactive probes for chemoselective bioimaging. However, these fluorescent anilines have been found to be unstable in aqueous physiological conditions due to the marked electrophilicity of their meso-position and hence its …

XantheneAqueous solutionPrimary (chemistry)NIR dye010405 organic chemistryHetero-xanthene dye[CHIM.ORGA]Chemical Sciences/Organic chemistryProcess Chemistry and TechnologyGeneral Chemical EngineeringFluorogenic enzyme substrateRosamine010402 general chemistry01 natural sciencesFluorescenceCombinatorial chemistry0104 chemical sciencesSulfonechemistry.chemical_compoundNucleophilechemistryElectrophileMoleculePyronin
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